Google ads will most likely be CPA ads and will have a "Google Certified Merchant" text that will try to increase people's trust in using the system.
Using this system, Google will find more information about what people actually buy and will update its ad ranking system.
Screenshots from Aneil Webber.
Note: these screenshots are not from Google, so the final product may look different.
Update: Here are some leaked screenshots from Google.
More about GBuy:
GBuy to launch this month
Make payments with Google